12 sourced pigment and dye records, including several with real documented health hazards — stated plainly, with a safety caveat, never as production instructions.
Ochre
Prehistory to present
Widely available and inexpensive — one of the most common historical pigments.
Egyptian blue
Ancient Egypt to the Roman period
Required deliberate high-temperature manufacture rather than simple mining or grinding, but became widely produced and traded once the process was established.

Ultramarine (natural)
Medieval period to 19th century (before synthetic ultramarine)
Extremely expensive — for centuries one of the costliest pigments available, often priced comparably to gold.

Indigo
Antiquity to the late 19th century (before synthetic indigo)
A major historical trade commodity; cost varied by region and period but was widely traded internationally.
Tyrian Purple
Antiquity
Enormously expensive; the sheer number of snails required made it one of the costliest dyes in antiquity.

Vermilion / Cinnabar
Antiquity to 19th century (largely replaced by cadmium red in the 20th)
Moderately to highly valued depending on period and source purity.
High toxicity
Lead White
Antiquity to the 20th century
Widely available and relatively inexpensive for most of its long history.
Historically fatal toxicity
Arsenic Greens (Scheele's Green and Paris Green)
Late 18th to late 19th century
Prized for its vividness relative to earlier green pigments, and widely adopted commercially.
Historically fatal toxicity

Prussian Blue
18th century to present
Significantly cheaper than natural ultramarine, making a strong blue pigment widely affordable for the first time.
Low toxicity
Mauveine
Mid-19th century
The first commercially successful synthetic dye — rapidly commercialised, making a vivid purple far more affordable than historical natural purples.
Low toxicity
Cochineal / Carmine
Pre-Columbian period to present
A major and highly valuable trade commodity after European contact with the Americas; still produced commercially today.
Synthetic Aniline Dyes (general)
Mid-to-late 19th century
Rapidly made a wide range of vivid, previously rare or expensive colours affordable and available at industrial scale for the first time.
Low toxicity