Natural · Antiquity to the late 19th century (before synthetic indigo)

Indigo dye is one of the oldest known dyes, traded across multiple continents for millennia before synthetic indigo production began in the late 19th century.
Indigo-dyed fibre varies considerably by dye strength, number of dips and how the yarn has aged — this is one specific dyed sample, not a definitive indigo shade."Indigo Dyed Yarn" by Loggie-log, public domain, via Wikimedia Commons