Dark blue reads as deep and saturated, often with a strong limbal ring that makes the iris look sharply outlined. Blue-grey reads as pale and desaturated. The two are rarely confused in good light; the confusion happens in dim conditions, where dark blue loses its depth and blue-grey loses its blue, and both converge on a similar muted appearance.
Neither dark blue nor blue-grey is separately recorded by classification systems, so both names describe positions on a range rather than defined groups.
Under-exposure flattens dark blue towards black; over-exposure flattens blue-grey towards white. A single image can misrepresent either in opposite directions.
No photograph or online colour-picker tool can definitively classify which of these categories a specific pair of eyes belongs to — classification is inherently somewhat subjective, and lighting/camera effects change the apparent result.