A clear blue iris reads as a definite colour; blue-grey reads as a blue that has had the saturation taken out of it. Placed side by side the difference is usually obvious; seen separately, the same eyes are often called blue by one person and blue-grey by another.
There is no saturation threshold at which blue becomes blue-grey, and only one of the two is a category studies record.
Exposure matters as much as white balance here: over-exposure drains saturation and can turn a clear blue iris into an apparent blue-grey in the image.
No photograph or online colour-picker tool can definitively classify which of these categories a specific pair of eyes belongs to — classification is inherently somewhat subjective, and lighting/camera effects change the apparent result.